Hydrogen-bonded porous solid derived from trimesic amide
نویسندگان
چکیده
منابع مشابه
Porous Hydrogen-Bonded Organic Frameworks.
Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are ...
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متن کاملSiloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs.
A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(ii) gave IMP-18 - a 3D MOF incorporating Si-O-Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(ii).
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 1997
ISSN: 1359-7345,1364-548X
DOI: 10.1039/a705339h